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One of the simplest and best known kinds of crystal is the ionic salt, of
which a typical example is sodium chloride, or ordinary table salt. The
fundamental components of an ionic salt are ions: atoms or molecules that have
become electrically charged by gaining or losing one more electrons. In forming
sodium chloride, for example, sodium atoms give up an electron (thereby becoming
positively charged) and chlorine atoms gain an electron (thereby becoming
negatively charged). The ions are attracted to one another by their opposite
charges, and they stack together compactly, like tightly packed spheres.
Recently, scientists at Michigan State University created a new kind of
crystal called an electride. In electrides, the anions (negative ions) are
completely replaced by electrons, which are trapped in naturally formed cavities
within a framework of regularly stacked cations (positive ions). Electrides are
the first examples of ionic salts in which all these anionic sites are occupied
solely by electrons.
Unlike other types of anions, anionic electrons do not behave as if they
were simple charged spheres. In particular, because of their low mass and their
tendency to interact with one another over great distances, they cannot be
“pinned down” to any one location. Instead, they wander close to and among the
atoms lining the cavity and interact with electrons in nearby cavities, perhaps
changing places with them.
The properties of an electride depend largely on the distance between the
cavities that hold trapped electrons. When the trapped electrons are far apart,
they do not interact strongly, and so behave somewhat like an array of isolated
negative charges. When they are closer together, they begin to display
properties associated with large ensembles of identical particles. When they are
still closer, the ensemble properties dominate and the electrons “delocalize”:
they are no longer tightly bound within individual cavities but are more or less
free to pass through the spaces within the framework of positive ions.
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